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Bases and Alkalis
A base is any metal oxide (contains oxide ions, O2-) or metal hydroxide (contains hydroxide ions, OH–).
An alkali is a base that is soluble in water. Alkalis produce hydroxide ions when dissolved in water.
Note: It is a common misconception that all hydroxides are alkalis.
Most of the metal hydroxides are, in fact, insoluble in water. Hence, they are bases, not alkalis.
Group (I) hydroxides are all alkalis. Example: Sodium hydroxide (NaOH), Lithium hydroxide (LiOH), Potassium hydroxide (KOH)
Other common alkalis include Calcium hydroxide (Ca(OH)2, Barium hydroxide Ba(OH)2 and aqueous ammonia (NH3 (aq)/ NH4OH (aq))
Some Metal oxides that are soluble in water to form alkalis
Sodium oxide: Na2O(s) + H2O(l) → 2NaOH(aq)
Potassium oxide: K2O(s) + H2O(l) → 2KOH(aq)